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An Introduction to Chemistry - Second Edition (Chapter 2)

Mark Bishop

Chiral Publishing Company

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Copyright © 2011 Mark Alton Bishop, publishing as Chiral Publishing Company, 1441 Manor Place, Monterey, CA 93940. All rights reserved. This publication is protected by copyright and permission should be obtained from Mark Bishop prior to any prohibited reproduction, storage in a retrieval system, or transmission in any form or by any means, electronic, mechanical, photocopying, recording, or likewise. To obtain permission(s) to use material from this work, please submit a written request to Chiral Publishing, 1441 Manor Place, Monterey, CA 93940. For information regarding permissions, send email to markbishop@chiralpublishing.com.

ISBN 978-0-9778105-8-1

CHAPTER 2

THE STRUCTURE OF MATTER AND THE CHEMICAL ELEMENTS

2.1 Solids, Liquids, and Gases

2.2 The Chemical Elements

2.3 The Periodic Table of the Elements

2.4 The Structure of the Elements

2.5 Common Elements

One doesn’t discover new lands without consenting to lose sight of the shore for a very long time.

Andre Gide

French Novelist and Essayist

In this chapter, we begin the journey that will lead you to an understanding of chemistry. Perhaps your ultimate educational goal is to know how the human body functions or to learn how the many parts of a shoreline ecosystem work together. You won’t get very far in these studies without a basic knowledge of the chemical principles underlying them. Even before talking about basic chemical principles, though, you must learn some of the language of chemistry and develop an image of the physical world that will help you to think like a chemist.

Many important tasks in life require that you learn a new language and new skills. When you are learning to drive a car, for example, your driving instructor might tell you that when two cars reach a four-way stop at the same time, the driver on the left must yield the right of way. This statement won’t mean anything to you unless you already know what a “four-way stop” is and what is meant by “yield” and “right of way”. To drive safely, you need to learn which of the symbols you see on road signs means “lane merges ahead” or “steep grade”. You need to learn procedures that will help you make lane changes and parallel park.

Chemistry, like driving a car, uses a language and skills of its own. Without a firm foundation in these fundamentals, a true understanding of chemistry is impossible. This chapter begins to construct that foundation by introducing some key aspects of the chemists’ view of matter.

Review Skills

The presentation of information in this chapter assumes that you can already perform the tasks listed below. You can test your readiness to proceed by answering the Review Questions at the end of the chapter. This might also be a good time to read the Chapter Objectives, which precede the Review Questions.

- Define matter. (Chapter 1 Glossary)

- Write the SI base units for mass and length and their abbreviations. (Section 1.4)

- Using everyday examples, describe the general size of a meter and a gram. (Section 1.4)

2.1 SOLIDS, LIQUIDS, AND GASES

A chemist’s primary interest, as described in Chapter 1, is the behavior of matter, but to understand the behavior of matter, we must first understand its internal structure. What are the internal differences between the granite of Half Dome in Yosemite, the olive oil added to your pasta sauce, and the helium in a child’s balloon? A simple model of the structure of matter will help us begin to answer this question.

A model is a simplified approximation of reality. For example, architects often build a model of a construction project before actual construction begins. The architect’s model is not an exact description of the project, but it is still very useful as a representation of what the structure will be like. Scientific models are like the architects’ models; they are simplified but useful representations of something real. In science, however, the models are not always physical entities. Sometimes they are sets of ideas instead.

In the last hundred years, there has been a tremendous increase in our understanding of the physical world, but much of that understanding is based on extremely complicated ideas and mathematics. The application of the most sophisticated forms of these modern ideas is difficult, and not very useful to those of us who are not well trained in modern physics and high-level mathematics. Therefore, scientists have developed simplified models for visualizing, explaining, and predicting physical phenomena. For example, we are about to examine a model that will help you visualize the tiny particles of the solid metal in a car’s engine block, the liquid gasoline in the car’s tank, and the gaseous exhaust fumes that escape from its tail pipe. The model will help you understand why solids have constant shape and volume at a constant temperature, why liquids have a constant volume but can change their shape, and why gases can easily change both their shape and volume. (OBJECTIVE 2) Our model of the structure of solids, liquids, and gases says that

- All matter is composed of tiny particles. (We will start by picturing these as tiny spheres.)

- These particles are in constant motion.

- The amount of motion is related to temperature. Increased temperature reflects increased motion. (Objective 3)

- Solids, gases, and liquids differ in the freedom of motion of their particles and in how strongly the particles attract each other.

Solids

Why does the metal in a car’s engine block retain its shape as you drive down the road while the fuel in the car’s gas tank conforms to the shape of the tank? What’s happening on the submicroscopic level when solid metal is melted to a liquid, and why can molten metal take the shape of a mold used to form an engine block? Our model will help us to answer these questions.

According to our model, the particles of a solid can be pictured as spheres held closely together by strong mutual attractions. (Figure 2.1). All the particles are in motion, bumping and tugging one another. Because they’re so crowded and exert such strong mutual attractions, however, they only jostle in place. Picture yourself riding on particle 1 in Figure 2.1. An instant before the time captured in the figure, your particle was bumped by particle 3 and sent toward particle 5. (The curved lines in the figure represent the momentary direction of each particle’s motion and its relative velocity.) This motion continues until the combination of a bump from particle 5 and tugging from particles 2, 3, and 4 quickly bring you back toward your original position. Perhaps your particle will now head toward particle 2 at a greater velocity than it had before, but again, a combination of bumps and tugs will send you back into the small space between the same particles. (OBJECTIVE 4) A ride on any of the particles in a solid would be a wild one, with constant changes in direction and velocity, but each particle will occupy the same small space and have the same neighbors.

(OBJECTIVE 5) When a solid is heated, the average speed of the moving particles increases. Faster-moving particles collide more violently, causing each particle to push its neighbors farther away. Therefore, an increase in temperature usually causes a solid to expand somewhat (Figure 2.1).

Liquids

If any solid is heated enough, the movements of the particles become sufficiently powerful to push the other particles around them completely out of position. Look again at Figure 2.1. If your particle is moving fast enough, it can push adjacent particles out of the way entirely and move to a new position. (OBJECTIVE 6) For those adjacent particles to make way for yours, however, they must push the other particles around them aside. In other words, for one particle to move out of its place in a solid, all of the particles must be able to move. The organized structure collapses, and the solid becomes a liquid.

(OBJECTIVE 7) Particles in a liquid are still close together, but there is generally more empty space between them than in a solid. Thus, when a solid substance melts to form a liquid, it usually expands to fill a slightly larger volume. Even so, attractions between the particles keep them a certain average distance apart, so the volume of the liquid stays constant at a constant temperature. On the other hand, because the particles in a liquid are moving faster and there is more empty space between them, the attractions are easily broken and reformed, and the particles change location freely. Eventually, each particle gets a complete tour of the container. (OBJECTIVE 8) This freedom of movement allows liquids to flow, taking on the shape of their container. It is this freedom of movement that allows liquid metal to be poured into a mold where it takes the shape of an engine block (Figure 2.2).

Figure 2.1

Particles of a Solid (OBJECTIVES 2, 4, 5)

Figure 2.2

Particles of a Liquid (OBJECTIVE 2)

Gases

If you’ve ever spilled gasoline while filling your car, you know how quickly the smell finds your nose. Our model can help you understand why.

Picture yourself riding on a particle in liquid gasoline. Because the particle is moving throughout the liquid, it will eventually come to the liquid’s surface. Its direction of movement may carry it beyond the surface into the space above the liquid, but the attraction of the particles behind it will most likely draw it back again. On the other hand, if your particle is moving fast enough, it can move far enough away from the other particles to break the attractions pulling it back. This is the process by which liquid is converted to gas. The conversion of liquid to gas is called vaporization or evaporation (Figure 2.3).

You might also have noticed, while pumping gasoline, that the fumes smell stronger on a hot day than on a cold day. When the gasoline’s temperature is higher, its particles are moving faster and are therefore more likely to escape from the liquid, so that more of them reach your nose.

Figure 2.3

The Process of Evaporation (OBJECTIVE 9)

(OBJECTIVE 2) The particles of a gas are much farther apart than in a solid or liquid. In the air around us, for example, the average distance between particles is about ten times the diameter of each particle. This leads to the gas particles themselves taking up only about 0.1% of the total volume. The other 99.9% of the total volume is empty space. In contrast, the particles of a liquid fill about 70% of the liquid’s total volume. According to the model, each particle in a gas moves freely in a straight-line path until it collides with another gas particle or with the particles of a liquid or solid. The particles are usually moving fast enough to break any attraction that might form between them, so after two particles collide, they bounce off each other and continue on their way alone.

Figure 2.4

Particles of a Gas (OBJECTIVE 2)

(OBJECTIVE 2) Picture yourself riding on a gas particle at the instant captured in Figure 2.4. You are so far away from any other particles that you think you are alone in the container. An instant later, you collide with a particle that seems to have come out of nowhere. The collision changes your direction and velocity. In the next instant, you are again moving freely, as if your particle was the only one in the universe.

(OBJECTIVE 10) Unlike the liquid, which has a constant volume, the rapid, ever-changing, and unrestricted movement of the gas particles allows gases to expand to fill any shape or volume of container. This movement also allows our cars’ exhaust gases to move freely out of the cars and into the air we breathe.

If you have a Flash-enabled device, you can review the information in this section and see particles of solids, liquids, and gases in motion at the textbook’s Web site.

2.2 THE CHEMICAL ELEMENTS

Chemists, like curious children, learn about the world around them by taking things apart. Instead of dissecting music boxes and battery-operated rabbits, however, they attempt to dismantle matter, because their goal is to understand the substances from which things are made. The model of the structure of matter presented in the last section describes the behavior of the particles in a solid, a liquid, or a gas. But what about the nature of the particles themselves? Are all the particles in a solid, liquid, or gas identical? And what are the particles made of? We begin our search for the answers to these questions by analyzing a simple glass of water with table salt dissolved in it.

We can separate this salt water into simpler components in a series of steps. First, heating can separate the salt and the water; the water will evaporate, leaving the salt behind. If we do the heating in what chemists call a distillation apparatus, the water vapor can be cooled back to its liquid form and collected in a separate container (Figure 2.5). Next, the water can be broken down into two even simpler substances–hydrogen gas and oxygen gas–by running an electric current through it. Also, we can melt the dry salt and then run an electric current through it, which causes it to break down into sodium metal and chlorine gas.

Figure 2.5

Distillation

Water can be separated from salt water on a small scale using a laboratory distillation apparatus.

Thus the salt water can be converted into four simple substances: hydrogen, oxygen, sodium, and chlorine (Figure 2.6 on the next page). Chemists are unable to convert these four substances into simpler ones. They are four of the building blocks of matter that we call elements, substances that cannot be chemically converted into simpler ones. (We will get a more precise definition of elements after we have explored their structure in more detail.)

The rest of this chapter is devoted to describing some common elements. Water, which consists of the elements hydrogen and oxygen, and salt, which consists of the elements sodium and chlorine, are examples of chemical compounds, which are described in Chapter 5. The mixture of salt and water is an example of a solution. Mixtures and solutions are described in Chapter 7.

Figure 2.6

Separation of Salt Water into Four Substances

Millions of simple and complex substances are found in nature or produced in the chemical laboratory, but the total number of elements that combine to form these substances is much, much smaller. By the year 2012, 118 elements had been discovered, but 28 of these elements are not found naturally on the earth, and chemists do not generally work with them. Of these 28 elements, 2 or 3 might exist in stars, but the rest are not thought to exist outside the physicist’s laboratory. (See Special Topic 2.1: Why Create New Elements?) Some of the elements found in nature are unstable; that is, they exist for a limited time and then turn into other elements in a process called radioactive decay. Of the 83 stable elements found in nature, many are rare and will not be mentioned in this text. The most important elements for our purposes are listed on Table 2.1.

Each of the elements is known by a name and a symbol. The names were assigned in several ways. Some of the elements, such as francium and californium, were named to honor the places where they were discovered. Some have been named to honor important scientists. An element discovered in 1982 has been named meitnerium to honor Lise Meitner (1878-1968), the Austrian-Swedish physicist and mathematician who discovered the element protactinium and made major contributions to the understanding of nuclear fission. Some names reflect the source from which scientists first isolated the element. The name hydrogen came from the combination of the Greek words for “water“(hydro) and “forming” (genes). Some elements, such as the purple element iodine, are named for their appearance. Iodos means violet in Greek.

Lise Meitner

The symbols for the elements were chosen in equally varied ways. Some are the first letter of the element’s name. For example, C represents carbon. Other symbols are formed from the first letter and a later letter in the name. When two letters are used, the first is capitalized and the second remains lowercase. Cl is used for chlorine and Co for cobalt. Some of the symbols come from earlier, Latin names for elements. For example, Na for sodium comes from the Latin natrium, and Au for gold comes from the Latin aurum, which means shining dawn. The most recently discovered elements have not been officially named yet. They are given temporary names and three-letter symbols.

Jewelry can be made from the elements gold, silver, copper, and carbon in the diamond form.

In your study of chemistry, it will be useful to learn the names and symbols for as many of the elements in Table 2.1 as you can. Ask your instructor which of the element names and symbols you will be expected to know for your exams.

2.3 THE PERIODIC TABLE OF THE ELEMENTS

Hanging on the wall of every chemistry laboratory, and emblazoned on many a chemist’s favorite mug or T-shirt, is one of chemistry’s most important basic tools, the periodic table of the elements (Figure 2.7). This table is like the map of the world on the wall of every geography classroom. If a geography instructor points to a country on the map, its location alone will tell you what the climate would be like and perhaps some of the characteristics of the culture. Likewise, you may not be familiar with the element potassium, but we shall see that the position of its symbol, K, on the periodic table, tells us that this element is very similar to sodium and that it will react with the element chlorine to form a substance that is very similar to table salt.

The elements are organized on the periodic table in a way that makes it easy to find important information about them. You will quickly come to appreciate how useful the table is when you know just a few of the details of its arrangement.

Table 2.1

Common Elements (OBJECTIVE 11)

aluminum, Al

argon, Ar

barium, Ba

beryllium, Be

boron, B

bromine, Br

cadmium, Cd

calcium, Ca

carbon, C

chlorine, Cl

chromium, Cr

copper, Cu

fluorine, F

gold, Au

helium, He

hydrogen, H

iodine, I

iron, Fe

lead, Pb

lithium, Li

magnesium, Mg

manganese, Mn

mercury, Hg

neon, Ne

nickel, Ni

nitrogen, N

oxygen, O

phosphorus, P

platinum, Pt

potassium, K

sillicon, Si

silver, Ag

sodium, Na

strontium, Sr

sulfur, S

tin, Sn

uranium, U

xenon, Xe

zinc, Zn

If you have a Flash-enabled device, you can practice converting between element names and symbols at the textbook’s Web site.

Figure 2.7

Periodic Table of the Elements (OBJECTIVES 12, 15, 17, 18)

The periodic table is arranged in such a way that elements in the same vertical column have similar characteristics. Therefore, it is often useful to refer to all the elements in a given column as a group or family. Each group has a number, and some have a group name. For example, the last column on the right is group 18, and the elements in this column are called noble gases.

(OBJECTIVE 12) In the United States, there are two common conventions for numbering the columns (Figure 2.7). Check with your instructor to find out which numbering system you are expected to know.

- Groups 1 to 18: The vertical columns can be numbered from 1 to 18. This text will use this numbering convention most often.

- Groups A and B: Some of the groups are also commonly described with a number and the letter A or B. For example, sometimes the group headed by N will be called group 15 and sometimes group 5A. The group headed by Zn can be called 12 or 2B. Because this convention is useful and is common, you will see it used in this text also. Some chemists use Roman numerals with the A- and B-group convention.

In short, the group headed by N can be 15, 5A, or VA. The group headed by Zn can be 12, 2B, or IIB.

(OBJECTIVE 13) The groups in the first two and last two columns are the ones that have names as well as numbers. You should learn these names; they are used often in chemistry.

(OBJECTIVE 14) Most of the elements are classified as metals, which means they have the following characteristics.

- Metals have a shiny metallic luster.

- Metals conduct heat well and in the solid form conduct electric currents.

- Metals are malleable, which means they are capable of being extended or shaped by the blows of a hammer. (For example, gold, Au, can be hammered into very thin sheets without breaking.)

There is more variation in the characteristics of the nonmetal elements. Some of them are gases at room temperature and pressure, some are solids, and one is a liquid. They have different colors and different textures. The definitive quality shared by all nonmetals is that they do not have the characteristics mentioned above for metals. For example, sulfur is a dull yellow solid that does not conduct heat or electric currents well and is not malleable. It shatters into pieces when hit with a hammer.

A few of the elements have some but not all of the characteristics of metals. These elements are classified as metalloids or semimetals. Authorities disagree to some extent concerning which elements belong in this category, but the elements in yellow boxes in the image on the left are commonly classified as metalloids.

(OBJECTIVE 15) The portion of the periodic table that contains the metallic elements is shown here in gray, and the portion that contains the nonmetallic elements is shown in light blue. The stair-step line that starts between B and Al on the periodic table and descends between Al and Si, Si and Ge, and so on separates the metallic elements from the nonmetallic elements. The metals are below and to the left of this line, and the nonmetals are above and to the right of it. Most of the elements that have two sides of their box forming part of the stair-step line are metalloids. Aluminum is usually considered a metal.

(OBJECTIVE 16) It is often useful to refer to whole blocks of elements on the periodic table. The elements in groups 1, 2, and 13 through 18 (the “A” groups) are sometimes called the representative elements. They are also called the main-group elements. The elements in groups 3 through 12 (the “B” groups) are often called the transition metals. The 28 elements at the bottom of the table are called inner transition metals.

(OBJECTIVE 17) The horizontal rows on the periodic table are called periods. There are seven periods in all. The first period contains only two elements, hydrogen1, H, and helium, He. (The symbol for hydrogen is placed in different positions on different periodic tables. On some, it is placed in group 1, and on other tables, it is found at the top of group 17. Although there are reasons for placing it in these positions, there are also reasons why it does not belong in either position. Therefore, on our periodic table, it is separate from both groups.) The second period contains eight elements: lithium, Li, through neon, Ne. The fourth period consists of eighteen elements: potassium, K, through krypton, Kr.

Note that the sixth period begins with cesium, Cs, which is element number 55, and barium, Ba, which is number 56, and then there is a gap which is followed by lutetium, Lu, element 71. The gap represents the proper location of the first row of the inner transition metals—that is, lanthanum, La, which is element number 57, through ytterbium, Yb, which is element 70. These elements belong in the sixth period. Similarly, the second row of inner transition metals, the elements actinium, Ac, through nobelium, No, belong in the seventh period between radium, Ra, and lawrencium, Lr.

(OBJECTIVE 18) At room temperature (20 °C) and normal pressures, most of the elements are solid, two of them are liquid (Hg and Br), and eleven are gas (H, N, O, F, Cl, and the noble gases).

Iodine is a solid, bromine is a liquid, and chlorine is a gas. Most elements are solid at room temperature.

EXERCISE 2.1 - Elements and the Periodic Table

(OBJECTIVES 12, 15, 16, 17, 18)

For each of the following, write each of the following that are not given (1) the name of the element, (2) the element symbol, (3) the group number on the periodic table, (4) whether it is a metal, nonmetal, or metalloid, (5) whether it is a representative element, transition metal, or inner transition metal, (6) the number of the period on the periodic table, and (7) whether it is a solid, liquid or gas at room temperature and pressure.

a. Al

b. silicon

c. Ni

d. sulfur

e. F

f. potassium

g. Hg

h. uranium (no group number)

i. Mn

j. calcium

k. group number 17 and 4th period

l. group number 1B and 5th period

m. group number 14 and nonmetal

EXERCISE 2.2 - Group Names and the Periodic Table

Write the name of the group on the periodic table to which each of the following elements belongs. (OBJECTIVE 13)

a. helium

b. Cl

c. magnesium

d. Na

2.4 THE STRUCTURE OF THE ELEMENTS

What makes one element different from another? To understand the answer to this question, you need to know about their internal structure. If you were to cut a piece of pure gold in half, and then divide one of those halves in half again and divide one of those halves in half, and continue to do that over and over, eventually the portion remaining could not be further divided and still be gold. This portion is a gold atom. The element gold consists of gold atoms, the element carbon consists of carbon atoms, and so on. To understand what makes one element different from another, we need to look inside the atom.

Scanning Tunneling Microscope Image of Silicon Atoms

Created by Benjamin Grosser, director of the imaging technology group at Beckman Institute from data supplied by Joe Lyding

The Atom

The atom is the smallest part of the element that retains the chemical characteristics of the element itself. (You will be better prepared to understand descriptions of the elements’ chemical characteristics after reading more of this book. For now, it is enough to know that the chemical characteristics of an element include how it combines with other elements to form more complex substances.) For our purposes, we can think of the atom as a sphere with a diameter of about 10−10 meters. This is about a million times smaller than the diameter of the period at the end of this sentence. If the atoms in your body were an inch in diameter, you would have to worry about bumping your head on the moon.

Because atoms are so small, there are a tremendous number of them in even a small sample of an element. A ½-carat diamond contains about 5 × 10^21 atoms of carbon. If these atoms, tiny as they are, were arranged in a straight line with each one touching its neighbors, the line would stretch from here to the sun.

If we could look inside the gold atom, we would find that it is composed of three types of particles: protons, neutrons, and electrons. (The physicists will tell you that the proton and neutron are themselves composed of simpler particles. Because it is not useful to the chemist to describe atoms in terms of these more fundamental particles, they will not be described here.) Every gold atom in nature, for example, has 79 protons, 79 electrons, and 118 neutrons. Gold is different from phosphorus, because natural phosphorus atoms have 15 protons, 15 electrons, and 16 neutrons.

The particles within the atom are extremely tiny. A penny weighs about 2.5 grams, and a neutron, which is the most massive of the particles in the atom, weighs only 1.6750 × 10-24 grams. The protons have about the same mass as the neutrons, but the electrons have about 2000 times less mass. Because the masses of the particles are so small, a more convenient unit of measurement has been devised for them. An atomic mass unit (also called the unified mass unit) is 1/12 the mass of a carbon atom that has 6 protons, 6 neutrons, and 6 electrons. The modern abbreviation for atomic mass unit is u, but amu is commonly used.

(OBJECTIVE 19) Protons have a positive charge, electrons have a negative charge, and neutrons have no charge. Charge, a fundamental property of matter, is difficult to describe. Most definitions focus less on what it is than on what it does. For example, we know that objects of opposite charge attract each other, and objects of the same charge repel each other. An electron has a charge that is opposite but equal in magnitude to the charge of a proton. We arbitrarily assign the electron a charge of −1, so the charge of a proton is considered to be +1.

The Nucleus

(OBJECTIVE 20) Modern atomic theory tells us that even though the protons and neutrons represent most of the mass of the atom, they actually occupy a very small part of the volume of the atom. These particles cling together to form the incredibly small core of the atom called the nucleus. Compared to the typical atom’s diameter, which we described earlier as being about 10-10 meters, the diameter of a typical nucleus is about 10-15 meters. Thus, almost all the mass of the atom and all of its positive charge are found in a nucleus of about 1/100,000 the diameter of the atom itself. If an atom were the size of the earth, the diameter of the nucleus would be just a little longer than the length of a football field. If the nuclei of the atoms in your body were about an inch in diameter, you’d have to stand on the dark side of the earth to avoid burning your hair in the sun.

The Electron

If I seem unusually clear to you, you must have misunderstood what I said.

Alan Greenspan, former head of the Federal Reserve Board

It is probably as meaningless to discuss how much room an electron takes up as to discuss how much room a fear, an anxiety, or an uncertainty takes up.

Sir James Hopwood Jeans,

English mathematician, physicist and astronomer (1877-1946)

(OBJECTIVE 20) Describing the modern view of the electron may not be as difficult as explaining the U.S. Federal Reserve Board’s monetary policy, but it is still a significant challenge. We do not think that electrons are spherical particles orbiting around the nucleus like planets around the sun. Scientists agree that electrons are outside the nucleus, but how to describe what they are doing out there or even what they are turns out to be a difficult task. Until the nature of electrons is described in more detail in Chapter 4, we will disregard the question of what electrons are and how they move and focus our attention only on the negative charge that they generate. We can visualize each electron as generating a cloud of negative charge that surrounds the nucleus. In Figure 2.8, we use the element carbon as an example.

Most of the carbon atoms in a diamond in a necklace have 6 protons, 6 neutrons, and 6 electrons. The protons and neutrons are in the nucleus, which is surrounded by a cloud of negative charge created by the 6 electrons. You will learn more about the shapes and sizes of different atoms’ electron clouds in Chapter 4. For now, we will continue to picture the electron clouds of all the atoms as spherical (Figure 2.8).

Figure 2.8

The Carbon Atom (OBJECTIVES 19-21)

Ions

Sometimes, when the elements form more complex substances, their atoms lose or gain electrons. Before this change, the atoms have an equal number of protons and electrons, and because protons and electrons have an equal but opposite charge, these atoms are initially uncharged overall. (OBJECTIVE 22) When an uncharged atom gains or loses one or more electrons, it forms a charged particle, called an ion. For example, when an atom loses one or more electrons, it will have more protons than electrons and more plus charge than minus charge. Thus, it will have an overall positive charge. An atom that becomes a positively charged ion is called a cation. For example, uncharged sodium atoms have 11 protons and 11 electrons. They commonly lose one of these electrons to form +1 cations. A sodium cation’s overall charge is +1 because its 11 protons have a charge of +11, and its remaining 10 electrons have a charge of −10. The sum of +11 and −10 is +1 (Figure 2.9). The symbol for a specific cation is written with the charge as a superscript on the right side of the element symbol. If the charge is +1, the convention is to write + (without the 1), so the symbol for the +1 sodium cation is Na+. Aluminum atoms commonly lose 3 of their electrons to form +3 cations. The cations are +3 because each aluminum cation has a charge of +13 from its 13 protons and a charge of −10 from its 10 remaining electrons. The sum is +3. The symbol for this cation is Al3+. (Notice that the 3 comes before the +.)

(OBJECTIVE 22) Some atoms can gain electrons. When an atom gains one or more electrons, it will have more electrons than protons and more minus charge than plus charge. An atom that becomes negatively charged due to an excess of electrons is called an anion, a negatively charged ion. For example, uncharged chlorine atoms have 17 protons and 17 electrons. They commonly gain 1 electron to form −1 anions. The anions are −1 because their 17 protons have a charge of +17, and their 18 electrons have a charge of −18, giving a sum of −1. The anion’s symbol is Cl-, again without the 1. As illustrated in Figure 2.9, oxygen atoms commonly form anions with a −2 charge, O2-, by gaining 2 electrons and therefore changing from eight protons and 8 electrons to 8 protons (+8) and ten electrons (−10).

Figure 2.9

Sodium and Oxygen Ions

EXAMPLE 2.1 - Cations and Anions

Identify each of the following as a cation or an anion, and determine the charge on each. (OBJECTIVE 22)

a. A nitrogen atom with 7 protons and 10 electrons.

b. A gold atom with 79 protons and 78 electrons.

Solution

a. 7 protons have a +7 charge, and 10 electrons have a −10 total charge for a sum of −3. Therefore, a nitrogen atom with 7 protons and 10 electrons is an anion.

b. 79 protons have a total charge of +79, and 78 electrons have a −78 total charge for a sum of +1. Therefore, a gold atom with 79 protons and 78 electrons is a cation.

Isotopes

Although all of the atoms of a specific element have the same number of protons (and the same number of electrons in uncharged atoms), they do not necessarily all have the same number of neutrons. For example, when the hydrogen atoms in a normal sample of hydrogen gas are analyzed, we find that of every 5000 atoms, 4999 have 1 proton and 1 electron, but 1 in 5000 of these atoms has 1 proton, 1 neutron, and 1 electron. This form of hydrogen is often called deuterium. Moreover, if you collected water from the cooling pond of a nuclear power plant, you would find that a very small fraction of its hydrogen atoms have 1 proton, 2 neutrons, and 1 electron (Figure 2.10). This last form of hydrogen, often called tritium, is unstable and therefore radioactive.

All of these atoms are hydrogen atoms because they have the chemical characteristics of hydrogen. For example, they all combine with oxygen atoms to form water. The chemical characteristics of an atom are determined by its number of protons (which is equal to the number of electrons if the atom is uncharged) and not by its number of neutrons. Because atoms are assigned to elements based on their chemical characteristics, an element can be defined as a substance whose atoms have the same number of protons. When an element has two or more species of atoms, each with the same number of protons but a different number of neutrons, the different species are called isotopes.

Figure 2.10

Isotopes of Hydrogen

Atomic Number and Mass Number

(OBJECTIVE 23) The number of protons in an atom—which is also the number of electrons in an uncharged atom—is known as the element’s atomic number. The atomic number can be found above each of the elements’ symbols on the periodic table. Because it displays the atomic numbers, the periodic table can be used to determine the number of protons and electrons in an uncharged atom of any element. For example, the atomic number of phosphorus is 15, so we know there are 15 protons and 15 electrons in each uncharged atom of phosphorus.

The sum of the numbers of protons and neutrons in the nucleus of an atom is called the atom’s mass number. Isotopes have the same atomic number but different mass numbers. To distinguish one isotope from another, the symbol for the element is often followed by the mass number of the isotope. For example, the mass number of the most common isotope of hydrogen, with one proton and no neutrons, is 1, so its symbol is H-1. The other natural isotope of hydrogen, with one proton and one neutron, has a mass number of 2 and a symbol of H-2. Tritium, H-3, the radioactive form of hydrogen, has a mass number of 3. All of these isotopes of hydrogen have an atomic number of 1.

Nineteen of the elements found in nature have only one naturally occurring form. For example, all the aluminum atoms found in nature have 13 protons and 14 neutrons. Their mass number is 27.

Number of Protons + Number of Neutrons = Mass Number

13 + 14 = 27

The other naturally occurring elements are composed of more than one isotope. For example, in a sample of the element tin, Sn, all the atoms have 50 protons, but tin atoms can have 62, 64, 65, 66, 67, 68, 69, 70, 72, or 74 neutrons. Thus tin has 10 natural isotopes with mass numbers of 112, 114, 115, 116, 117, 118, 119, 120, 122, and 124 (Figure 2.11).

Figure 2.11

Isotopes of Tin

The tin in these tin cans is composed of ten different isotopes.

Learn about a special notation used to describe isotopes at the textbook’s Web site.

EXERCISE 2.3 - Cations and Anions

Identify each of the following as a cation or an anion, and determine the charge on each. (OBJECTIVE 22)

a. a magnesium atom with 12 protons and 10 electrons.

b. a fluorine atom with 9 protons and 10 electrons.

SPECIAL TOPIC 2.1 WHY CREATE NEW ELEMENTS?

At the Gesellschaft fur Schwerionenforschung (GSI), or Society for Heavy-Ion Research, in Germany, scientists create new elements by bombarding one kind of atom with another kind in the expectation that some of them will fuse. For example, for two weeks in 1994, the scientists bombarded a lead-208 target with a beam of nickel-62 atoms, producing four atoms of element 110, with a mass number of 269. Likewise, during 18 days in December of that year, they bombarded a bismuth-209 target with nickel-64 atoms, creating three atoms of element 111, with a mass number of 272.

Some of the best minds in physics are working on such projects, and spending large amounts of money on the necessary equipment. Yet the newly created atoms are so unstable that they decay into other elements in less than a second. Do these results justify all of the time, money, and brainpower being poured into them? Would scientists’ efforts be better spent elsewhere? Why do they do it?

One of the reasons these scientists devote themselves to the creation of new elements is to test their theories about matter. For example, the current model being used to describe the nucleus of the atom suggests there are “magic” numbers of protons and neutrons that lead to relatively stable isotopes. The numbers 82, 126, and 208 are all magic numbers, exemplified by the extreme stability of lead-208, which has 82 protons and 126 neutrons. Other magic numbers suggest that an atom with 114 protons and 184 neutrons would also be especially stable. Researchers at the Flerov Laboratory of Nuclear Reactions in Dubna, Russia, were able to make two isotopes of element 114 (with 173 and 175 neutrons) by bombarding plutonium targets with calcium atoms. Both isotopes, particularly the heavier one, were significantly more stable than other isotopes of comparable size.

The technology developed to create these new elements is also being used for medical purposes. In a joint project with the Heidelberg Radiology Clinic and the German Cancer Research Center, GSI has constructed a heavy-ion therapy unit for the treatment of inoperable cancers. Here, the same equipment used to accelerate beams of heavy atoms toward a target in order to make new elements is put to work shooting beams of carbon atoms at tumors. When used on deep-seated, irradiation-resistant tumors, the carbon-particle beam is thought to be superior to the traditional radiation therapy. Because the heavier carbon atoms are less likely to scatter, and because they release most of their energy at the end of their path, they are easier to focus on the cancerous tumor.

2.5 COMMON ELEMENTS

Most people look at a gold nugget and see a shiny metallic substance that can be melted down and made into jewelry. A chemist looks at a substance such as gold and visualizes the internal structure responsible for those external characteristics. Now that we have discussed some of the general features of atoms and elements, we can return to the model of solid, liquid, and gas structures presented in Section 2.1 and continue in our quest to visualize the particle nature of matter.

Gas, Liquid, and Solid Elements

(OBJECTIVE 24) In Section 2.1, we pictured gases as independent spherical particles moving in straight-line paths in a container that is mostly empty space. This image is most accurate for the noble gases (He, Ne, Ar, Kr, Xe, and Rn): each noble gas particle consists of a single atom. When we picture the helium gas in a helium-filled balloon, each of the particles in our image is a helium atom containing two protons and two neutrons in a tiny nucleus surrounded by a cloud of negative charge generated by two electrons (Figure 2.12).

Figure 2.12

Helium Gas (OBJECTIVE 24)

The particles in hydrogen gas are quite different. Instead of the single atoms found in helium gas, the particles in hydrogen gas are pairs of hydrogen atoms. Each hydrogen atom has only one electron, and single, or “unpaired,” electrons are less stable than electrons that are present as pairs. (Stability is a relative term that describes the resistance to change. A stable system is less likely to change than an unstable system.) To gain the greater stability conferred by pairing, the single electron of one hydrogen atom can pair up with a single electron of another hydrogen atom. The two electrons are then shared between the two hydrogen atoms and create a bond that holds the atoms together. Thus hydrogen gas is described as H_2. We call this bond between atoms due to the sharing of two electrons a covalent bond. The pair of hydrogen atoms is a molecule, which is an uncharged collection of atoms held together with covalent bonds. Two hydrogen atoms combine to form one hydrogen molecule.

(OBJECTIVE 25) The negative charge-cloud created by the electrons in the covalent bond between hydrogen atoms surrounds both of the hydrogen nuclei (Figure 2.13).

Figure 2.13

Hydrogen Electron Cloud

Even though the shape depicted in Figure 2.13 is a better description of the H_2 molecule’s electron cloud, there are two other common ways of illustrating the H_2 molecule. The first image in Figure 2.14 shows a space-filling model. This type of model emphasizes individual atoms in the molecule more than the image in Figure 2.13 does but still provides a somewhat realistic idea of the electron-charge clouds that surround the atoms. The second image in Figure 2.14 is a ball-and-stick model, in which balls represent atoms and sticks represent covalent bonds. This model gives greater emphasis to the bond that holds the hydrogen atoms together.

Figure 2.14

Molecular Models

Combining space-filling molecular models with our gas model, Figure 2.15 depicts hydrogen gas as being very similar to helium gas, except each of the particles is a hydrogen molecule.

Figure 2.15

Hydrogen Gas (OBJECTIVE 24)

(OBJECTIVE 26) Because hydrogen molecules are composed of two atoms, they are called diatomic. The elements nitrogen, oxygen, fluorine, chlorine, bromine, and iodine are also composed of diatomic molecules, so they are described as N_2, O_2, F_2, Cl_2, Br_2, and I_2. Like the hydrogen atoms in H2 molecules, the two atoms in each of these molecules are held together by a covalent bond that is due to the sharing of two electrons. Nitrogen, oxygen, fluorine, and chlorine are gases at room temperature and pressure, so a depiction of gaseous N_2, O_2, F_2, and Cl_2 would be very similar to the image of H_2 in Figure 2.15.

Bromine, which is a liquid at room temperature, is pictured like the liquid shown in Figure 2.2, except that each of the particles is a diatomic molecule (Figure 2.16).

Figure 2.16

Liquid Bromine, Br_2 (OBJECTIVE 24)

(OBJECTIVE 24) Solid iodine consists of a very ordered arrangement of I_2 molecules. In order to give a clearer idea of this arrangement, the first image in Figure 2.17 on the next page shows each I_2 molecule as a ball-and-stick model. The second image shows the close packing of these molecules in the iodine solid. Remember that the particles of any substance, including solid iodine, are in constant motion. The solid structure presented in Figure 2.1 applies to iodine, except we must think of each particle in it as being an I_2 molecule.

Figure 2.17

Solid Iodine, I_2 (OBJECTIVE 24)

If you have a Flash-enabled device, you can review the information in this section and see particles of neon, oxygen, bromine, and iodine in motion at the textbook’s Web site.

Metallic Elements

The metallic elements are used for a lot more than building bridges and making jewelry. Platinum is used in a car’s catalytic converter to help decrease air pollution. Titanium is mixed with other metals to construct orthopedic appliances, such as artificial hip joints. Zinc is used to make dry cell batteries. Some of the characteristics of metallic elements that give them such wide applications can be explained by an expanded version of the model of solids presented in Section 2.1. (One of the characteristics of a useful model is that it can be expanded to describe, explain, and predict a greater variety of phenomena.)

(OBJECTIVE 24) According to the expanded model, each atom in a metallic solid has released one or more electrons, and these electrons move freely throughout the solid. When the atoms lose the electrons, they become cations. The cations form the structure we associate with solids, and the released electrons flow between them like water flows between islands in the ocean. This model, often called the sea of electrons model, can be used to explain some of the definitive characteristics of metals. For example, the freely moving electrons make metallic elements good conductors of electric currents.

Figure 2.18 shows a typical arrangement of atoms in a metallic solid and also shows how you might visualize one plane of this structure. Try to picture a cloud of negative charge, produced by mobile electrons, surrounding the cations in the solid.

Figure 2.18

Typical Structure of a Metallic solid (OBJECTIVE 27)

You have just completed your first big step on the road to understanding chemistry. The new knowledge of the elements that you have gained from this chapter will help you with Chapter 3, where you will learn how elements combine to form more complex substances. An understanding of elements and the substances they form will prepare you to learn about the chemical changes that these substances undergo in yourself and in the world around you.

CHAPTER GLOSSARY

Model A simplified approximation of reality.

Solid The state in which a substance has a definite shape and volume at a constant temperature.

Liquid The state in which a substance has a constant volume at a constant temperature but can change its shape.

Gas The state in which a substance can easily change shape and volume.

Evaporation or vaporization The conversion of a liquid to a gas.

Element A substance that cannot be chemically converted into simpler substances; a substance in which all of the atoms have the same number of protons and therefore the same chemical characteristics.

Group All the elements in a given column on the periodic table; also called a family.

Family All the elements in a given column on the periodic table; also called a group.

Metals The elements that (1) have a metallic luster, (2) conduct heat and electric currents well, and (3) are malleable.

Malleable Capable of being extended or shaped by the blows of a hammer.

Nonmetals The elements that do not have the characteristics of metals. Some of the nonmetals are gases at room temperature and pressure, some are solids, and one is a liquid. Various colors and textures occur among the nonmetals.

Metalloids or semimetals The elements that have some but not all of the characteristics of metals.

Representative elements The elements in groups 1, 2, and 13 through 18 (the “A” groups) on the periodic table; also called main-group elements.

Main-group elements The elements in groups 1, 2, and 13 through 18 (the “A” groups) on the periodic table; also called representative elements.

Transition metals The elements in groups 3 through 12 (the “B” groups) on the periodic table.

Inner transition elements The 28 elements at the bottom of the periodic table.

Periods The horizontal rows on the periodic table.

Atom The smallest part of an element that retains the chemical characteristics of the element.

Atomic mass unit (u or amu) Unit of measurement for the masses of particles; 1/12 the mass of a carbon atom that has 6 protons, 6 neutrons, and 6 electrons.

Proton A positively charged particle found in the nucleus of an atom.

Electron A negatively charged particle found outside the nucleus of an atom.

Neutron An uncharged particle found in the nucleus of an atom.

Nucleus The extremely small, positively charged core of the atom.

Ion Any charged particle, whether positively or negatively charged.

Cation An ion formed from an atom that has lost one or more electrons and thus has become positively charged.

Anion An ion formed from an atom that has gained one or more electrons and thus has become negatively charged.

Isotopes Atoms that have the same number of protons but different numbers of neutrons. They have the same atomic number but different mass numbers.

Atomic number The number of protons in an atom’s nucleus. It establishes the element’s identity.

Mass number The sum of the number of protons and neutrons in an atom’s nucleus.

Covalent bond A link between atoms that results from their sharing two electrons.

Molecule An uncharged collection of atoms held together with covalent bonds.

Space-filling model A way of representing a molecule to show a somewhat realistic image of the electron-charge clouds that surround the molecule’s atoms.

Ball-and-stick model A representation of a molecule that uses balls for atoms and sticks for covalent bonds.

Diatomic Composed of paired atoms. The diatomic elements are H_2, N_2, O_2, F_2, Cl_2, Br_2, and I_2.

If you have a Flash-enabled device, you can test yourself on the glossary terms at the textbook’s Web site.

CHAPTER OBJECTIVES

The goal of this chapter is to teach you to do the following.

1. Define all of the terms in the Chapter Glossary.

Section 2.1 Solids, Liquids, and Gases

2. Describe solids, liquids, and gases in terms of the particle nature of matter, the degree of motion of the particles, and the degree of attraction between the particles.

3. Describe the relationship between temperature and particle motion.

4. Explain why solids have a definite shape and volume at a constant temperature.

5. Explain why solids usually expand when heated.

6. Describe the structural changes that occur when a solid is converted into a liquid by heating.

7. Explain why most substances expand when they change from a solid to a liquid.

8. Explain why liquids adjust to take the shape of their container and why they have a constant volume at a constant temperature.

9. Describe the structural changes that occur in the conversion of a liquid to a gas.

10. Explain why gases expand to take the shape and volume of their container.

Section 2.2 The Chemical Elements

11. Give the names and symbols for the common elements. (Check with your instructor to find out which names and symbols you need to know.)

Section 2.3 The Periodic Table of the Elements

12. Given a periodic table, identify the number of the group to which each element belongs. (Check with your instructor to find out which numbering system you are expected to know.)

13. Given a periodic table, identify the alkali metals, alkaline earth metals, halogens, and noble gases.

14. List the characteristics of metals.

15. Given a periodic table, classify each element as a metal, nonmetal, or metalloid (semimetal).

16. Given a periodic table, classify each element as a representative element (or main-group element), a transition metal, or an inner transition metal.

17. Given a periodic table, write or identify the number of the period on the table to which each element belongs.

18. Classify each element as a solid, liquid, or gas at room temperature.

Section 2.4 The Structure of the Elements

19. Give the abbreviations, charges, and relative masses of protons, neutrons, and electrons.

20. Describe the nuclear model of the atom, including the general location of the protons, neutrons, and electrons, the relative size of the nucleus compared to the size of the atom, and the modern description of the electron.

21. Describe the carbon atom, including a rough sketch that shows the negative charge created by its electrons.

22. Given the number of protons and electrons in a cation or anion, determine its charge.

23. Given an isotope’s atomic number, state the number of protons in each of its atoms, and vice versa.

Section 2.5 Common Elements

24. Describe the following substances in terms of the nature of the particles that form their structure: the noble gases, hydrogen gas, nitrogen gas, oxygen gas, fluorine gas, chlorine gas, bromine liquid, and iodine solid.

25. Describe the hydrogen molecule, including a rough sketch of the charge cloud created by its electrons.

26. List the diatomic elements (H_2, N_2, O_2, F_2, Cl_2, Br_2, and I_2).

27. Describe the “sea of electrons” model for metallic structure.

REVIEW QUESTIONS

1. Define the term matter.

2. Look around you. What do you see that has a length of about a meter? What do you see that has a mass of about a gram?

KEY IDEAS

Complete the following statements by writing one of these words or phrases in each blank.

10−10

10−15

1/100,000

24

114

0.1%

70%

99.9%

atoms

atomic mass

atomic numbers

attract

chemical

cloud

empty space

escape

expand

expands

extended or shaped

flow

gains

gas

impossible

liquid

loses

molecule

motion

neutrons

one-twelfth

particles

protons

rapid, ever-changing, and unrestricted

repel

simplified but useful

simpler

single atom

solid

straight-line path

sun

temperature

ten times

vertical column

weighted

3. Scientific models are like architects’ models; they are _____________ representations of something real.

4. According to the model presented in this chapter, all matter is composed of tiny _____________.

5. According to the model presented in this chapter, particles of matter are in constant _____________.

6. According to the model presented in this chapter, the amount of motion of particles is proportional to _____________.

7. Solids, gases, and liquids differ in the freedom of motion of their particles and in how strongly the particles _____________ each other.

8. An increase in temperature usually causes a solid to _____________ somewhat.

9. Particles in a liquid are still close together, but there is generally more _____________ between them than in a solid. Thus, when a solid substance melts to form a liquid, it usually _____________ to fill a slightly larger volume.

10. The freedom of movement of particles in a liquid allows liquids to _____________, taking on the shape of their container.

11. When a liquid’s temperature is higher, its particles are moving faster and are therefore more likely to _____________ from the liquid.

12. The average distance between particles in a gas is about _____________ the diameter of each particle. This leads to the gas particles themselves taking up only about _____________ of the total volume. The other _____________ of the total volume is empty space. In contrast, the particles of a liquid fill about _____________ of the liquid’s total volume.

13. According to our model, each particle in a gas moves freely in a(n) _____________ until it collides with another gas particle or with the particles of a liquid or solid.

14. A liquid has a constant volume, but the _____________ movement of the gas particles allows gases to expand to fill a container of any shape or volume.

15. Elements are substances that cannot be chemically converted into _____________ ones.

16. By the year 2000, _____________ elements had been discovered, but _____________ of these elements are not found naturally on the earth, and chemists do not generally work with them.

17. The periodic table is arranged in such a way that elements in the same _____________ have similar characteristics.

18. Metals are malleable, which means they are capable of being _____________ by the blows of a hammer.

19. At room temperature (20 °C) and normal pressures, most of the elements are _____________, two of them are _____________ (Hg and Br), and eleven are _____________ (H, N, O, F, Cl, and the noble gases).

20. For our purposes, we can think of the atom as a sphere with a diameter of about _____________ meter.

21. A ½-carat diamond contains about 5 × 10^21 atoms of carbon. If these atoms, tiny as they are, were arranged in a straight line with each one touching its neighbors, the line would stretch from here to the _____________.

22. We know that objects of opposite charge attract each other and that objects of the same charge _____________ each other.

23. The diameter of a typical nucleus is about _____________ meter.

24. Nearly all the mass of the atom and all of its positive charge are found in a nucleus of about _____________ the diameter of the atom itself.

25. Chemists use a model for electrons in which each electron is visualized as generating a(n) _____________ of negative charge that surrounds the nucleus.

26. When an atom _____________ one or more electrons, it will have more protons than electrons and more plus charge than minus charge. Thus it becomes a cation, which is an ion with a positive charge.

27. When an atom _____________ one or more electrons, it then has more electrons than protons and more minus charge than plus charge. Thus it becomes an anion, which is an ion with a negative charge.

28. Although all of the atoms of a specific element have the same number of _____________ (and the same number of electrons in uncharged atoms), they do not necessarily all have the same number of _____________.

29. Atoms are assigned to elements on the basis of their _____________ characteristics.

30. Because it displays the _____________, the periodic table can be used to determine the number of protons and electrons in an uncharged atom of any element.

31. Each noble gas particle consists of a(n) _____________.

32. Hydrogen gas is very similar to helium gas, except that each of the particles is a hydrogen _____________.

CHAPTER PROBLEMS

Section 2.1 Solids, Liquids, and Gases

For each of the questions in this section, illustrate your written answers with simple drawings of the particles that form the structures of the substances mentioned. You do not need to be specific about the nature of the particles. Think of them as simple spheres, and draw them as circles.

33. If you heat white sugar very carefully, it will melt. (OBJECTIVES 2, 3, 4 AND 6)

a. Before you begin to heat the sugar, the sugar granules maintain a constant shape and volume. Why?

b. As you begin to heat the solid sugar, what changes are taking place in its structure?

c. What happens to the sugar’s structure when sugar melts?

34. If the pistons and cylinders in your car engine get too hot, the pistons can get stuck in the cylinders, causing major damage to the engine. Why does this happen? (OBJECTIVE 9)

35. Ethylene glycol, an automobile coolant and antifreeze, is commonly mixed with water and added to car radiators. Because it freezes at a lower temperature than water and boils at a higher temperature than water, it helps to keep the liquid in your radiator from freezing or boiling. (OBJECTIVES 2, 3, 8 AND 9)

a. At a constant temperature, liquid ethylene glycol maintains a constant volume but takes on the shape of its container. Why?

b. The ethylene glycol-water mixture in your car’s radiator heats up as you drive. What is happening to the particles in the liquid?

c. If you spill some engine coolant on your driveway, it evaporates without leaving any residue. Describe the process of evaporation of liquid ethylene glycol, and explain what happens to the ethylene glycol particles that you spilled.

36. When a small container of liquid ammonia is opened in a classroom, in a short time everyone in the room can smell it. (OBJECTIVES 2, 9 AND 10)

a. Describe the changes that take place when liquid ammonia vaporizes to form a gas.

b. Why does the gaseous ammonia expand to fill the whole room?

c. Why does the gaseous ammonia occupy a much greater volume than the liquid ammonia?

37. As the summer sun heats up the air at the beach, what is changing for the air particles?

38. A drop of food coloring is added to water. With time, it spreads evenly through the water so that the mixture is all the same color.

a. Describe what is happening to the food coloring and water particles as the coloring spreads into the water.

b. When a drop of food coloring is added to two bowls of water, one at 20 °C and the other at 30 °C, the coloring spreads more quickly in the bowl at the higher temperature. Why?

39. A gaseous mixture of air and gasoline enters the cylinders of a car engine and is compressed into a smaller volume before being ignited. Explain why gases can be compressed.

Section 2.2 The Chemical Elements and Section 2.3 The Periodic Table

40. Write the chemical symbols that represent the following elements. (OBJECTIVE 11)

a. chlorine

b. zinc

c. phosphorus

d. uranium

41. Write the chemical symbols that represent the following elements. (OBJECTIVE 11)

a. hydrogen

b. calcium

c. mercury

d. xenon

42. Write the chemical symbols that represent the following elements. (OBJECTIVE 11)

a. iodine

b. platinum

c. boron

d. gold

43. Write the element names that correspond to the following symbols. (OBJECTIVE 11)

a. C

b. Cu

c. Ne

d. K

44. Write the element names that correspond to the following symbols. (OBJECTIVE 11)

a. O

b. Br

c. N

d. Si

45. Write the element names that correspond to the following symbols. (OBJECTIVE 11)

a. Ba

b. F

c. Sr

d. Cr

46. For each of the following, write each of the following that are not given (1) the name of the element, (2) the element symbol, (3) the group number on the periodic table, (4) whether it is a metal, nonmetal, or metalloid, (5) whether it is a representative element, transition metal, or inner transition metal, (6) the number of the period on the periodic table, and (7) whether it is a solid, liquid or gas at room temperature and pressure. (OBJECTIVES 11, 12, 15, 16, 17)

a. Na

b. tin

c. He

d. nickel

e. Ag

f. aluminum

g. Si

h. group number 16 and 3rd period

i. group number 2B and 6th period

47. For each of the following, write each of the following that are not given (1) the name of the element, (2) the element symbol, (3) the group number on the periodic table, (4) whether it is a metal, nonmetal, or metalloid, (5) whether it is a representative element, transition metal, or inner transition metal, (6) the number of the period on the periodic table, and (7) whether it is a solid, liquid or gas at room temperature and pressure. (OBJECTIVES 11, 12, 15, 16, 17)

a. Mg

b. lead

c. argon

d. Cd

e. chromium

f. Fe

k. group number 7B and 4th period

l. group number 1A and 2nd period

m. group number 18 and 5th period

48. Write the name of the group or family to which each of the following belongs. (OBJECTIVE 13)

a. bromine

b. neon

c. potassium

d. beryllium

49. Write the name of the group or family to which each of the following belongs. (OBJECTIVE 13)

a. strontium

b. lithium

c. iodine

d. xenon

50. Identify each of the following elements as a solid, a liquid, or a gas at room temperature and pressure. (OBJECTIVE 18)

a. krypton, Cr

b. Br

c. antimony, Sb

d. F

e. germanium, Ge

f. S

51. Identify each of the following elements as a solid, a liquid, or a gas at room temperature and pressure. (OBJECTIVE 18)

a. chlorine

b. Se

c. mercury

d. W

e. xenon

f. As

52. Which two of the following elements would you expect to be most similar: lithium, aluminum, iodine, oxygen, and potassium?

53. Which two of the following elements would you expect to be most similar: nitrogen, chlorine, barium, fluorine, and sulfur?

54. Write the name and symbol for the elements that fit the following descriptions.

a. the halogen in the third period

b. the alkali metal in the fourth period

c. the metalloid in the third period

55. Write the name and symbol for the elements that fit the following descriptions.

a. the noble gas in the fifth period

b. the alkaline earth metal in the sixth period

c. the representative element in group 3A and the third period

56. Which element would you expect to be malleable, manganese or phosphorus? Why?

57. Which element would you expect to conduct electric currents well, aluminum or iodine? Why?

Section 2.4 The Structure of the Elements

58. Describe the nuclear model of the atom, including the general location of the protons, neutrons, and electrons; the relative size of the nucleus compared to the size of the atom; and the modern description of the electron. (OBJECTIVE 20)

59. Describe the carbon atom, and make a rough sketch. (OBJECTIVE 21)

60. Identify each of the following as a cation or an anion, and determine the charge on each. (OBJECTIVE 22)

a. A lithium ion with 3 protons and 2 electrons

b. A sulfur ion with 16 protons and 18 electrons

61. Identify each of the following as a cation or an anion, and determine the charge on each.

a. An iodine ion with 53 protons and 54 electrons

b. An iron ion with 26 protons and 23 electrons

62. Write definitions of the terms atomic number and mass number. Which of these can vary without changing the element? Why? Which of these cannot vary without changing the element? Why?

63. Write the atomic number for each of the following elements.

a. oxygen

b. Mg

c. uranium

d. Li

e. lead

f. Mn

64. Write the atomic number for each of the following elements.

a. sodium

b. As

c. strontium

d. Pu

e. iron

f. Se

65. Explain how two atoms of oxygen can be different.

66. Write the name and symbol for the elements that fit the following descriptions.

a. 27 protons in the nucleus of each atom.

b. 50 electrons in each uncharged atom.

c. 18 electrons in each +2 cation.

d. 10 electrons in each −1 anion.

67. Write the name and symbol for the elements that fit the following descriptions.

a. 78 protons in the nucleus of each atom.

b. 42 electrons in each uncharged atom.

c. 80 electrons in each +3 cation.

d. 18 electrons in each −2 anion.

Section 2.5 Common Elements

68. Describe the hydrogen molecule, including a rough sketch of the electron-charge cloud created by its electrons. (OBJECTIVE 25)

69. Write definitions for the terms atom and molecule and use them to explain the difference between hydrogen atoms and hydrogen molecules.

70. Describe the structure of each of the following substances, including a description of the nature of the particles that form each structure. (OBJECTIVE 24)

a. neon gas

b. bromine liquid

c. nitrogen gas

71. Describe the structure of each of the following substances, including a description of the nature of the particles that form each structure. (OBJECTIVE 24)

a. chlorine gas

b. iodine solid

c. argon gas

72. Describe the sea-of-electrons model for metallic solids. (OBJECTIVE 27)

Discussion Question

73. When you heat solid iodine, it goes directly from solid to gas. Describe the process by which iodine particles escape from the solid to the gas form. What characteristics must iodine particles have to be able to escape? Draw a picture to illustrate your answer.

SELECTED ANSWERS

Chapter 2 Exercises

2.1 aluminum, Al, 13, 3A or IIIA, metal, representative (or main-group) element, 3, solid; silicon, Si, 14, 4A or IVA, metalloid, representative (or main-group) element, 3, solid; nickel, Ni, 10, 8B or VIIIB, metal, transition metal, 4, solid; sulfur, S, 16, 6A or VIA, nonmetal, representative (or main-group) element, 3, solid; fluorine, F, 17, 7A or VIIA, nonmetal, representative (or main-group) element, 2, gas; potassium, K, 1, 1A or IA, metal, representative (or main-group) element, 4, solid; mercury, Hg, 12, 2B or IIB, metal, transition metal, 6, liquid; uranium, U, (No group number), metal, inner transition metal, 7, solid; manganese, Mn, 7, 7B or VIIB, metal, transition metal, 4, solid; calcium, Ca, 2, 2A or IIA, metal, representative (or main-group) element, 4, solid; bromine, Br, 17, nonmetal, representative (or main-group) element, 4, liquid; silver, Ag, 1B, metal, transition metal, 5, solid; carbon, C, 14, nonmetal, representative (or main-group) element, 2, solid

2.2 (a) noble gases

(b) halogens

(c) alkaline earth metals

(d) alkali metals

2.3 (a) +2 cation   (b) -1 anion.

Chapter 2 Review Questions

1. Matter is anything that occupies space and has mass.

2. The distance between the floor and a typical doorknob is about one meter. A penny weighs about three grams.

Chapter 2 Key Ideas

3. simplified but useful

5. motion

7. attract

9. empty space, expands

11. escape

13. straight-line path

15. simpler

17. vertical column

19. solid, liquid, gas

21. sun

23. 10-15

25. cloud

27. gains

29. chemical

31. single atom

Chapter 2 Problems

33(a) Strong attractions between the particles keep each particle at the same average distance from other particles and in the same general position with respect to its neighbors.

(b) The velocity of the particles increases, causing more violent collisions between them. This causes them to move apart, so the solid expands. See Figure 2.1.

(c) The particles break out of their positions in the solid and move more freely throughout the liquid, constantly breaking old attractions and making new ones. Although the particles are still close together in the liquid, they are more disorganized, and there is more empty space between them.

35(a) The attractions between liquid particles are not strong enough to keep the particles in position like the solid. The movement of particles allows the liquid to take the shape of its container. The attractions are strong enough to keep the particles at the same average distance, leading to constant volume.

(b) The velocity of the particles increases, so they will move throughout the liquid more rapidly. The particles will collide with more force. This causes them to move apart, so the liquid expands slightly. (c) Particles that are at the surface of the liquid and that are moving away from the surface fast enough to break the attractions that pull them back will escape to the gaseous form. The gas particles will disperse throughout the neighborhood as they mix with the particles in the air. See Figures 2.3 and 2.4.

37. The air particles are moving faster.

39. There is plenty of empty space between particles in a gas.

40(a) Cl   (b) Zn   (c) P   (d) U

43(a) carbon  (b) copper  (c) neon  (d) potassium

46. sodium, Na, 1 or 1A or IA, metal, representative (or main-group) element, 3; tin, Sn, 14 or 4A or IVA, metal, representative element, 5; helium, He, 18 or 8A or VIIIA, nonmetal, representative (or main-group) element, 1; nickel, Ni, 10 or 8B or VIIIB, metal, transition metal, 4; silver, Ag, 11 or 1B or IB, metal, transition metal, 5; aluminum, Al, 13 or 3A or IIIA, metal, representative (or main-group) element, 3; silicon, Si, 14 or 4A or IVA, metalloid, representative (or main-group) element, 3; sulfur, S, 16, nonmetal, representative (or main-group) element, 3; mercury, Hg, 2B, metal, transition metal, 6

58. (a) halogens

(b) noble gases

(c) alkali metals

(d) alkaline earth metals

50. (a) gas  (b) liquid  (c) solid  (d) gas  (e) solid  (f) solid

52. lithium and potassium

54. (a) chlorine, Cl  (b) potassium, K  (c) silicon, Si

56. Because manganese is a metal, we expect it to be malleable.

58. Protons and neutrons are in a tiny core of the atom called the nucleus, which has a diameter of about 1/100,000 the diameter of the atom. The position and motion of the electrons are uncertain, but they generate a negative charge that is felt in the space that surrounds the nucleus.

60. (a) +1 cation   (b) -2 anion

63. (a) 8  (b) 12  (c) 92  (d) 3  (e) 82  (f) 25

66. (a) cobalt, Co  (b) tin, Sn  (c) calcium, Ca  (d) fluorine, F

68. See Figure 2.13. The cloud around the two hydrogen nuclei represents the negative charge cloud generated by the two electrons in the covalent bond that holds the atoms together in the H_2 molecule.

70. (a) Neon is composed of separate neon atoms. Its structure is very similar to the structure of He shown in Figure 2.12.

(b) Bromine is composed of Br_2 molecules. See Figure 2.16.

(c) Nitrogen is composed of N_2 molecules. Its structure is very similar to the structure of H2 shown in Figure 2.15.

72. Each atom in a metallic solid has released one or more electrons, allowing the electrons to move freely throughout the solid. When the atoms lose these electrons, they become cations, which form the organized structure we associate with solids. The released electrons flow between the stationary cations like water flows between islands in the ocean. See Figure 2.18.

PHOTO CREDITS

All photos not credited were taken by the author, Mark Bishop. Page numbers are for the printed text.

page 33, Dragos Voica/bigstockphoto.com

page 34, Scott Rothstein/bigstockphoto.com

page 41, Courtesy of the Hahn-Meitner Institute

page 46, Courtesy of Benjamin Grosser and Joe Lyding at the Beckman Institute

page 47, Anita Patterson/bigstockphoto.com

page 52, Alex Bramwell/bigstockphoto.com

page 53, Alan Crosthwaite/bigstockphoto.com

page 56, Andreas Guskos/bigstockphoto.com

page 63, Nicola Gavin/bigstockphoto

Table of Contents

Title Page

Copyright

Chapter 2 The Structure of Matter and the Chemical Elements

2.1 Solids, Liquids, and Gases

2.2 The Chemical Elements

2.3 The Periodic Table of the Elements

2.4 The Structure of the Elements

2.5 Common Elements

Chapter Glossary

Chapter Objectives

Review Questions

Key Ideas

Chapter Problems

Selected Answers

Photo Credits